Carbon Molecular Sieves – A kinetic study

نویسندگان

  • Andreas Möller
  • Joachim Guderian
  • Marcus Lange
  • Jens Möllmer
چکیده

Carbon Molecular Sieves (CMS) are unique materials which are widely used in processes based on pressure swing adsorption (PSA) for nitrogen generation by oxygen removal from air [1, 2, 3] and for the enrichment of methane from biogas or landfill gas [4]. Steadily improved CMS were launched in the last years to cover these applications. The recent materials are characterized by higher sorption capacities, compared to conventional CMS. However, in the common applications (e.g. PSA) the kinetic parameters, like kinetic selectivities etc. are the most important properties. Therefore, investigations of sorption kinetics and their temperature dependence are of great interest.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Preparation of Carbon Molecular Sieves from Pistachio Shell and Walnut Shell for Kinetic Separation of Carbon Monoxide, Hydrogen, and Methane

In this study, two Carbon Molecular Sieves using Pistachio shell (CMS P) and Walnut shell (CMS W) were prepared by a chemical vapor deposition method and used for pressure swing adsorption and separation of CO/H2 and CO/CH4. Adsorption isotherms of gases obtained for both CMS’s. The Dubinin-Radushkevich isotherm model was used for comparing pore volum...

متن کامل

An exceptional kinetic quantum sieving separation effect of hydrogen isotopes on commercially available carbon molecular sieves.

The quantum sieving effect of H2/D2 at 77 K on commercially available carbon molecular sieves (1.5GN-H and 3KT-172) was studied. An exceptional reverse kinetic quantum effect is observed on 1.5GN-H where D2 diffuses much faster than H2 with a ratio of up to 5.83 at low pressure, and the difference is still very evident even as the pressure increases up to 1 bar. D2 also diffuses faster than H2 ...

متن کامل

Adsorption Properties of Carbon Molecular Sieves Prepared by a Co-carbonization Process

Carbon molecular sieves (CMSs) are microporous carbon materials whose special textural characteristics enable kinetic separation of gas mixtures, i.e., separation as a result of differences in the diffusion rates of the species involved. For a CMS to be useful for gas separation, it must possess a narrow pore size distribution (PSD) consisting of pore mouths of molecular sizes and a relatively ...

متن کامل

Templated Growth of Carbon Nanotubes on Nickel Loaded Mesoporous MCM-41 and MCM-48 Molecular Sieves

Chemical vapor deposition was employed to synthesize carbon nanotubes with Ni-loaded MCM-41 and MCM-48 as catalysts and acetylene as precursor at 750°C. Mesoporous Ni MCM-41 and Ni MCM-48 molecular sieves were synthesized by a hydrothermal method and were characterized by XRD and N2 adsorption isotherm. The catalytically synthesized carbon materials were characterized with Raman spectroscopy, N...

متن کامل

The kinetic parameters of drug compounds adsorption onto mesoporous materials

The discovery of mesoporous molecular sieves, MCM-41, which possesses a regular hexagonalarray of uniform pore openings, aroused a worldwide resurgence in this field. This is not onlybecause it has brought about a series of novel mesoporous materials with various compositionswhich may find applications in catalysis, adsorption, and guest-host chemistry, but also it hasopened a new avenue for cr...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2013